A buffer is a solution that resists changes in pH when small amounts of an acid or a base are added to it. In biology, buffers play an important role in maintaining the pH of physiological fluids within a narrow range that is compatible with the function of enzymes and other biomolecules.
In cells and tissues, the pH of the cytosol, the extracellular fluid, and the lumen of organelles such as the mitochondria and the endoplasmic reticulum is carefully regulated. This is necessary because many enzymes and other biomolecules are sensitive to changes in pH and can become denatured or lose activity if the pH deviates from their optimal range. For example, the enzymes involved in the citric acid cycle, which is a key metabolic pathway that occurs in the mitochondria, function optimally at a pH of around 7.4.
There are several mechanisms that cells use to maintain the pH of their internal environments. One of these mechanisms is the use of buffers. Buffers are chemical compounds that can accept or donate protons (H+ ions) without significant changes in their own concentration or pH. This allows them to absorb excess protons or donate protons as needed to maintain a relatively constant pH.
In cells, the most important buffers are the proteins and small organic molecules that can accept or donate protons. Examples of these include amino acids, such as histidine and lysine, and small organic molecules, such as phosphate and bicarbonate.
The bicarbonate buffer system is particularly important in the regulation of pH in the extracellular fluid, such as in the blood. The bicarbonate buffer system consists of carbonic acid (H2CO3) and bicarbonate (HCO3-), which can accept or donate protons as needed to maintain a constant pH. When the pH of the blood becomes too acidic, bicarbonate ions accept protons to form carbonic acid, which then decomposes into water and carbon dioxide. The carbon dioxide is then exhaled through the lungs, and the water is eliminated through the kidneys.
In summary, buffers are chemical compounds that play an important role in maintaining the pH of physiological fluids within a narrow range that is compatible with the function of enzymes and other biomolecules. They do this by absorbing excess protons or donating protons as needed to maintain a relatively constant pH. Buffers are especially important in cells and tissues, where they help to regulate the pH of the cytosol, the extracellular fluid, and the lumen of organelles.